Solid Electrolyte Interphase

Abstract Lithium-sulfur (Li-S) batteries promise the next-generation energy storage. ACS Applied Materials & Interfaces 8: 12211- 12220, 2016. 5−8 In particular, formation of SEI layers from reduced solvent products during charging causes both bene!cial and deleterious e"ects. Pham, Rodrigo Rodriguez, Sindhu S. A solid state electrochemical cell, comprising: a lithium metal anode; a cathode capable of absorbing and release of lithium ions; and a solid state electrolyte arranged between the lithium metal anode and the cathode; wherein an artificial interphase layer is located between the solid electrolyte and the lithium metal anode, the artificial. Despite numerous studies, the evolution mechanism of the SEI layer and specific roles of polysulfides and other electrolyte components are still unclear. However, current technology is limited in charging rate, power density, reliability, and safety. 有机溶剂常常在充电时破坏石墨的结构,导致其剥脱,并在其表面形成固体电解质膜(solid electrolyte interphase,SEI)导致电极钝化。 有机溶剂还带来易燃、易爆等安全性问题。. electrolytes with graphite negative electrodes, and the result shows that unlike the ethylene carbonate (EC)-based electrolyte, the FEC-based electrolyte (EC was totally replaced by FEC) is incapable of forming a protective and effective solid electrolyte interphase (SEI) that protects the electrolyte from runaway reduction on the graphite. In this respect, the choice of binders, carbon, electrolyte, and the morphology of the silicon itself plays a critical role in improving capacity retention. The solid electrolyte interphase (SEI), which forms spontaneously at the electrode-electrolyte interface, plays a critical role in the performance and safety of Li-ion batteries, but little is known about its structure from in-situ observations. We discover that a solid electrolyte interphase (SEI)-like interfacial layer between Li and SSE plays a critical role in alleviating the growth of dendritic Li, providing new insights into the interface between SSE and Li metal to enable future all solid-state batteries. The Solid-Electrolyte InterphaseThis video describes the basic development of the solid-electrolyte interphase (SEI) during the formation process of a lithium-ion battery. Toward understanding the microscopic mechanism of this observation, the dependency of the solid electrolyte interphase (SEI) film formation on the FEC concentration has been investigated in a propylene carbonate (PC)-based electrolyte solution by using the Red Moon method. There has been a push for solid-state electrolytes for lithium ion batteries to improve the safety of the batteries that power our world. Polymer-inorganic solid-electrolyte interphase for stable The solid-electrolyte interphase (SEI) is pivotal in stabilizing lithium metal anodes for rechargeable batteries. Three major components of a Li-ion. Solid Electrolyte Interphase ist eine bisher kaum verstandene Grenzflächenschicht, die aus der partiellen Zersetzung von Batterieelektrolyten in der Gegenwart von Lithium resultiert. 5−8 In particular, formation of SEI layers from reduced solvent products during charging causes both bene!cial and deleterious e"ects. Polymer electrolyte has moderate contact with cathode due to the elasticity and deformability of organic polymers. Of specific. 6 eV is clearly observed at the surface before sputtering (0 time). Li reacts instantly in contact with liquid electrolytes and rapidly forms an SEI film. The additive comprises a di-substituted malonate silyl ester compound, in which the hydrogens of the malonate methylene group are replaced by substituents R1 (e. A model system, epitaxial graphene on SiC, was used to provide a well-defined surface that is. Solid-electrolyte interphase (SEI) is the key component that enables all advanced electrochemical devices, the best representative of which is Li-ion battery (LIB). electrolyte, 12M lithium bis(fluorosulfonyl)imide (LiFSI) salt in DME solvent (12M LiFSI/DME), that can ef-fectively suppress both the Li dendritic growth on the anode and the polysulfide shuttle reactions on the cathode side. This study was conducted to understand effects of some of key factors (i. For the sake of this article, we will stick to the solid electrolyte interface. However, despite its overwhelming beneficial features, its large-scale commercialization is hampered due to unavoidable challenges such as colossal volume change during (de-)alloying, inherent low electronic and ionic conductivities, low Coulombic efficiency, unstable/dynamic solid electrolyte interphase (SEI), electrolyte drying etc. The SEI is often assumed to grow thicker on the carbon anode surface during cycling, eventually rendering it electrochemically inactive. Bingbin Wu,a Shanyu Wang,b Joshua Lochala,a David Desrochers,a Bo Liu,c Wenqing Zhang,d Jihui Yang*b and Jie Xiao*ae. It is even more important for high energy density electrodes such as Li metal anodes, which. For the sake of this article, we will stick to the solid electrolyte interface. K+ reduces lithium dendrite growth by forming a thin, less-resistive solid electrolyte interphase Sean M. Lucht Department of Chemistry, University of Rhode Island, Kingston, Rhode Island 02881, USA 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO (6, IRU(QHUJ\ (QYLURQPHQWDO6FLHQFH. Solid Electrolyte Interphase on Native Oxide-Terminated Silicon Anodes for Li-Ion Batteries The solid electrolyte interphase (SEI) is a passivation layer naturally formed on battery electrodes. Materials Science and Engineering, Johns Hopkins University, 2009 A dissertation submitted in partial fulfillment of the requirements for the Degree of Doctor of Philosophy. New solid-electrolyte interphase may boost prospects for rechargeable Li-metal batteries 12 March 2019 Rechargeable lithium metal batteries with increased energy density, performance, and safety may be possible with a newly-developed, solid-electrolyte interphase (SEI), according to Penn State researchers. President George H. The passivating solid electrolyte interphase (SEI) layer forms at the surface of the negative-electrode active material in lithium-ion cells. It overcame the growth of dendrites resulting from inadequate nucleation density but not dendrite growth into the depletion layer, which scales with the layer’s thickness, i. – Unstable SEI (solid electrolyte interphase) layer formed on electrode surface whch traps Li leading to capacity loss – Gas generated due to electrolyte decomposition on the electrode surface. Note that some people also called Solid Electrolyte Interface as Solid Electrolyte Interphase (SEI), both the terms are used interchangeably overall research papers and hence it is hard to argue on which is the correct term. It involves charge transfer at the interface between lithium and solid electrolyte interphase (SEI), lithium cation migration across the SEI barrier to the SEI/electrolyte interface, and diffusion of solvated ions into electrolyte. Battery performance, irreversible charge “loss”, rate capability, cyclability, exfoliation of graphite and safety are highly dependent on the quality of the SEI. To gain new insights into the formation of the solid electrolyte interphase (SEI), as a basis for the safe and efficient use of new anode materials, we studied SEI formation on silicon and lithium titanate (LTO) anodes by electrochemical impedance spectroscopy (EIS) and ex situ X-ray photoelectron spectroscopy (XPS) measurements. Silicon nanowires (SiNWs) have the potential to perform as anodes for lithium-ion batteries with a much higher energy density than graphite. There is also potential for improvements in the conductivity of lithium ions through solid-state electrolytes that could even surpass traditional flammable liquid electrolytes. pc客户端连续签到 7天抢福利 pc客户端 免费蓝光播放 pc客户端 3倍流畅播放 pc客户端 提前一小时追剧 pc客户端 自动更新下载剧集. The SEI is formed through chemical and particularly electrochemical side reactions of electrolyte components in the first charging cycle(s) after manufacturing. Rechargeable lithium metal batteries with increased energy density, performance, and safety may be possible with a newly-developed, solid-electrolyte interphase (SEI), according to Penn State researchers. There is also potential for improvements in the conductivity of lithium ions through solid-state electrolytes that could even surpass traditional flammable liquid electrolytes. Solid Electrolyte Interfaces (SEI). Nathan, Andrei D. Submitted to Energy and Environmental Science, 2019. The formation and evolution of the solid electrolyte interphase (SEI) film on the surface of natural graphite spheres in the electrolyte of 1 M LiPF6 in ethylene carbonate (EC) and dimethyl carbonate (DMC) (volume ratio 1:1) were investigated with use of focused ion beam (FIB) technology. In Situ X‑ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode Sudeshna Chattopadhyay,§,† Albert L. Enjoy the videos and music you love, upload original content, and share it all with friends, family, and the world on YouTube. Unraveling the Structure of Iron(III) Oxalate Tetrahydrate and Its Reversible Li Insertion Capability. The SEI film is due to electrochemical reduction of species present in the electrolyte. However, the unstable and static solid electrolyte interphase (SEI) can be destroyed by the dynamic Li plating/stripping behavior on the Li anode surface, leading to side reactions and Li dendrites growth. Jayalekshmi was not involved in the study, but her team has recently developed a novel type of solid polymer electrolyte (SPE) based on a polymer blend of PEO and PVP. Here, a significantly improved cycle life of 1000 cycles (80% capacity retention) on a practically insoluble organic cathode material, anthraquinone‐1,5‐disulfonic acid sodium salt, is realized, in KIBs through a solid‐electrolyte interphase (SEI) regulation strategy by ether‐based electrolytes. Second, we introduce ultra-thin graphene films as artificial solid electrolyte interphase (SEI) on the surface of a porous zinc anode to improve the cycling stability of ReHAB system. This solid-state electrolyte coating may be regarded as an artificial solid-electrolyte interphase (ASEI) [2]. Brown, Jiyeon Kim, and Brett L. Role of Solution Structure in Solid Electrolyte Interphase the Solid Electrolyte Interphase in Li-Ion Electrodes in Li Ion Batteries. Thus, a decrease of the viscosity of the electrolyte results in an increase of the ionic conductivity. A new concept of forming solid electrolyte interphases (SEI) in situ in an ionic conducting Li 1. Varying the concentration of PP13*TFSI ionic liquid can change the electrolyte solution structure and thus optimize the solid electrolyte interphase (SEI) on the graphite anode. How is Solid Electrolyte Interface (energy storage) abbreviated? SEI stands for Solid Electrolyte Interface (energy storage). Kurzfassung. Abstract Lithium-sulfur (Li-S) batteries promise the next-generation energy storage. Morphology, thickness, mechanical and chemical properties of SEI are important for safety and cycling performance of lithium-ion batteries. SEI - Solid Electrolyte Interface. The aqueous phase of margarine contains water and / or milk or milk products. Pedro de Souza, Kyle C. Lucht Department of Chemistry, University of Rhode Island, Kingston, Rhode Island 02881, USA 7KLV (OHFWURQLF6XSSOHPHQWDU\0DWHULDO (6, IRU(QHUJ\ (QYLURQPHQWDO6FLHQFH. Li1, Haiying Wang2, Seong H. *FREE* shipping on qualifying offers. This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The highly concentrated electrolyte along with the robust solid electrolyte interphase (SEI) formed therein. 5−8 In particular, formation of SEI layers from reduced solvent products during charging causes both bene!cial and deleterious e"ects. However, one of the issues facing Li-S batteries is the high reactivity of the Li metal, leading to serious interfacial side reactions; the other is the dendritic Li growth that can usually breach the solid electrolyte interphase (SEI) applied for mitigating side reactions. Unocic, Xiao-Guang Sun, Robert L. A paper on their work is published in the journal. The SEI film is due to electrochemical reduction of species present in the electrolyte. Available from: Analía Leticia Soldati, Laura Cecilia Baqué, Horacio Esteban Troiani and Adriana Cristina Serquis (October 17th 2012). This book carefully analyzes and discusses the most recent findings and advances on this topic. It is even more important for high energy density electrodes such as Li metal anodes, which. *FREE* shipping on qualifying offers. An unstable solid electrolyte interphase (SEI) and accompanying Li metal dendrites are the key impediments to commercialization of high-energy lithium metal batteries (LMBs). This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. This unique structure shows a high ionic conductivity, low interface resistance with electrode, and can suppress the. Polymer-inorganic solid-electrolyte interphase for stable The solid-electrolyte interphase (SEI) is pivotal in stabilizing lithium metal anodes for rechargeable batteries. This passivation layer of SEI prevents further loss of Li and electrolyte caused by their continued reaction (Lu et al. They see it as a power storage "game changer. Kim 3, Thomas E. However, when silicon electrodes are lithiated, they form a solid-electrolyte interphase (SEI) at their surface. ABSTRACT: Electrolytes additives are ubiquitous and indispensable in all electrochemical devices. The damage to the solid electrolyte layer is due to the mechanical volume change in Ge metal during lithium-ion insertion (charging) and extraction (discharge), which causes cracks and pulverization of this layer that lead to loss of electrode contact and dissolution of the solid electrolyte layer into the electrolyte. ARTICLE Operando X-ray photoelectron spectroscopy of solid electrolyte interphase formation and evolution in Li 2S-P 2S 5 solid-state electrolytes Kevin N. 5−8 In particular, formation of SEI layers from reduced solvent products during charging causes both bene!cial and deleterious e"ects. , 2015; Shin et al. To gain new insights into the formation of the solid electrolyte interphase (SEI), as a basis for the safe and efficient use of new anode materials, we studied SEI formation on silicon and lithium titanate (LTO) anodes by electrochemical impedance spectroscopy (EIS) and ex situ X-ray photoelectron spectroscopy (XPS) measurements. Solid-electrolyte interphase (SEI) layer is an organic-inorganic composite layer that allows Li + transport across but blocks electron flow across and prevents solvent diffusing to electrode surface. Model Studies on the Solid Electrolyte Interphase Formation on Graphite Electrodes in Ethylene Carbonate and Dimethyl Carbonate: Highly Oriented Pyrolytic Graphite [in press]. the electrolyte (the so-called 'solid-electrolyte interphase', SEI). Posting Title Postdoctoral Researcher - Solid-Electrolyte Interphase Location CO - Golden Position…See this and similar jobs on LinkedIn. Overall experimental results confirm the majority of species suggested by the simulation. The stability of a battery is strongly dependent on the feature of solid electrolyte interphase (SEI). The Solid-Electrolyte InterphaseThis video describes the basic development of the solid-electrolyte interphase (SEI) during the formation process of a lithium-ion battery. When appropriate organic solvents are used as the electrolyte, the solvent decomposes on initial charging and forms a solid layer called the solid electrolyte interphase, which is electrically insulating yet provides significant ionic conductivity. NEI is actively involved in producing different compositions of sulfide-based solid electrolyte materials, including our own patent-pending LSPS. Adsorption and Thermal Decomposition of Electrolytes on Nanometer Magnesium Oxide: An in Situ 13C MAS NMR Study The structural and chemical evolution of electrolyte constituents at the nanometric MgO surface were identified, providing a fundamental understanding of heterogeneous interphase evolution. This issue is further complicated by the existence of ultrathin solid electrolyte interphase (SEI) covering the electrode, forming a complex. The LiF-rich SEI successfully suppresses the penetration of Li dendrites into SSEs, while the low electronic conductivity and the intrinsic electrochemical stability of LiF block side reactions between the SSEs and Li. Three major components of a Li-ion. The solid electrolyte interphase (SEI) is a protecting layer formed on the negative electrode of Li-ion batteries as a result of electrolyte decomposition, mainly during the first cycle. Depending on the properties of the decomposition products, the interphase may lead to an increase in interfacial resistances and a decrease. Electrode/Electrolyte Interphase Characterization in Solid Oxide Fuel Cells, Hydrogen Energy - Challenges and Perspectives, Dragica Minic, IntechOpen, DOI: 10. – Unstable SEI (solid electrolyte interphase) layer formed on electrode surface whch traps Li leading to capacity loss – Gas generated due to electrolyte decomposition on the electrode surface. The anodes treated with layers of graphene oxide and sulfophenyl groups delivered reversible capacities which were 39% and 85% higher than the untreated. The aqueous phase of margarine contains water and / or milk or milk products. Our solid-state batteries provide a major improvement in energy density, safety, and reliability compared to the best Li-ion cells available. The SEI is formed from solvent and electrolytic salt that is electrochemicall reduced to oligomers and inorganic crystals on the silicon surfaces. The SEI film is due to electrochemical reduction of species present in the electrolyte. In this sense, the principle and the classification of film-forming additives for lithium ion secondary batteries are described. Carney, Alexis Grimaud, Livia Giordano, Nir Pour, Hao-Hsun Chang,David P. File:SEI layer formation on silicon. ACS Applied Materials & Interfaces 8: 12211- 12220, 2016. Posting Title Postdoctoral Researcher - Solid-Electrolyte Interphase Location CO - Golden Position…See this and similar jobs on LinkedIn. In fact, for the majority of Li-metal batteries with cathodes that do not contain lithium, the initial cycle for the anode is stripping, instead of deposition. Introduction Lithium metal is recognized as the optimal choice for anode mate-rial to achieve high energy density batteries because it has low negative. New solid-electrolyte interphase may boost prospects for rechargeable Li-metal batteries 12 March 2019 Rechargeable lithium metal batteries with increased energy density, performance, and safety may be possible with a newly-developed, solid-electrolyte interphase (SEI), according to Penn State researchers. Solid-state electrolytes (SSEs) are receiving great interest because their high mechanical strength and transference number could potentially suppress Li dendrites and their high electrochemical stability allows the use of high-voltage cathodes, which enhances the energy density and safety of batteries. It is important to understand what SEI is at a high level, as this component is one of the main contributing factors to Li-ion battery aging and resistance. Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation. electrolytes with graphite negative electrodes, and the result shows that unlike the ethylene carbonate (EC)-based electrolyte, the FEC-based electrolyte (EC was totally replaced by FEC) is incapable of forming a protective and effective solid electrolyte interphase (SEI) that protects the electrolyte from runaway reduction on the graphite. Klavetter, Adam Heller, & C. For this reason, the attention of the community has been mainly focusing on surface layer free electrolytes, while reductively. 240 sentence examples: 1. It involves charge transfer at the interface between lithium and solid electrolyte interphase (SEI), lithium cation migration across the SEI barrier to the SEI/electrolyte interface, and diffusion of solvated ions into electrolyte. composite material. (2019) Electron transfer in the solid-electrolyte interphase. The use of the artificial solid electrolyte interphase enables rapid diffusion and stable deposition of lithium to inhibit the formation of dendrites. Rezasadeh-Kalehbasti, Liu, L. , the current density. Mallouk1 and Donghai Wang 4*. Sitting between the lithium metal of the battery and its electrolytes is the solid-electrolyte interphase (SEI), and it has been a roadblock to developing better. New solid-electrolyte interphase may boost prospects for rechargeable Li-metal batteries 12 March 2019 Rechargeable lithium metal batteries with increased energy density, performance, and safety may be possible with a newly-developed, solid-electrolyte interphase (SEI), according to Penn State researchers. They see it as a power storage "game changer. Brown, Jiyeon Kim, and Brett L. Researchers have developed a promising new cathode and electrolyte system that replaces expensive metals and traditional liquid electrolyte with lower cost transition metal fluorides and a solid. T1 - Nanoscale Mechanics of the Solid Electrolyte Interphase on Lithiated-Silicon Electrodes. (Nanowerk News) Researchers have proposed an efficient and stable dual-phase lithium metal anode for Li-S batteries, containing polysulfide-induced solid electrolyte interphase and nanostructured graphene framework at Tsinghua University, appearing on ACS Nano ("Dual-Phase Lithium Metal Anode. Destructive processes may be controlled by the tailored formation of a solid-electrolyte interphase (SEI) that separates the lithium anode from the electrolyte, but still conducts lithium ions. However, the findings here shed new light on this assumption. Read "The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling, Carbon" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. perature can shed more light on parametrising the properties of the Solid Electrolyte Interphase (SEI); the identification of which, using an electrochemical model, is systematically addressed in this work. A passivation layer called the solid electrolyte interphase (SEI) is formed on electrode surfaces from decomposition products of electrolytes. Nathan, Andrei D. solid electrolyte, the decomposition products of the solid elec-trolyte would form as an interphase at the interfaces between solid electrolyte and electronic conductive additives. Here, we illustrate how advanced spectroscopic analysis can help to understand the chemical reactions and morphology progression that occurs at electrode/ electrolyte interfaces, with the solid-electrolyte interphase (SEI) formation on hydrogenated amorphous Si-based anodes [using 1 M LiPF 6 in a 1:1 mixture of ethylene carbonate and diethyl. Available from: Analía Leticia Soldati, Laura Cecilia Baqué, Horacio Esteban Troiani and Adriana Cristina Serquis (October 17th 2012). It is a self-limiting process where the formation of an SEI passivates further side reactions. It also acts as a mechanical barrier to suppress lithium dendritic growth. To shed light on the formation process and structure of the solid electrolyte interphase (SEI) layer on native oxide-terminated silicon wafer anodes from a carbonate-based electrolyte (LP30), we combined in situ synchrotron X-ray reflectivity, linear sweep voltammetry, ex situ X-ray photoelectron spectroscopy, and first principles calculations. The rapid chemical decomposition of the ionic liquid was shown to form a solid electrolyte interphase composed of the breakdown products of the ionic liquid components in the absence of an applied voltage. Simulation and Experiment on Solid Electrolyte Interphase (SEI) Morphology Evolution and Lithium-Ion Diffusion Pengjian Guan, Lin Liu,∗,z and Xianke Lin Department of Mechanical Engineering, The University of Kansas, Lawrence, Kansas 66045, USA. During charging and discharging, lithium ions shuttle between the cathode and anode through an electrolyte, the battery component that separates the two electrodes and is conductive to ions, but not to electrons. Varying the concentration of PP13*TFSI ionic liquid can change the electrolyte solution structure and thus optimize the solid electrolyte interphase (SEI) on the graphite anode. This paper derives a nonlinear, electrolyte-enhanced, single particle model (NESPM) that includes aging due to solid electrolyte interphase layer growth. Distamycin A tends to lack stability in aqueous solution and it is not recommended to store it in solution. A paper on their work is published in the journal. 1016 DOI Values for: 10. 5−8 In particular, formation of SEI layers from reduced solvent products during charging causes both bene!cial and deleterious e"ects. Effect of electrolytes on the structure and evolution of the solid electrolyte interphase (SEI) in Li-ion batteries A molecular dynamics study Sang Pil Kim, Adri Van Duin , Vivek B. title = "Surface chemistry and morphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes", abstract = "Silicon nanowires (SiNWs) have the potential to perform as anodes for lithium-ion batteries with a much higher energy density than graphite. This passivation layer of SEI prevents further loss of Li and electrolyte caused by their continued reaction (Lu et al. solid electrolyte, the decomposition products of the solid elec-trolyte would form as an interphase at the interfaces between solid electrolyte and electronic conductive additives. Electrode/Electrolyte Interphase Characterization in Solid Oxide Fuel Cells 281 the electrolyte to the anode material, where it oxidizes the hydrogen molecule. The model is validated with experimental full charge, discharge, HEV cycle, and aging data from 4. The chemical structure of the surface and interior of the SEI strongly affects the cycling performance of the anode. SERV/CROSSREF: 2: EMAIL: 2018-09-04 17:53:41Z: support. File:SEI layer formation on silicon. An unstable solid electrolyte interphase (SEI) and accompanying Li metal dendrites are the key impediments to commercialization of high-energy lithium metal batteries (LMBs). The mechanism of Li + transport through the solid electrolyte interphase (SEI), a passivating film on electrode surfaces, has never been clearly elucidated despite its overwhelming importance to Li-ion battery operation and lifetime. T1 - Nanoscale Mechanics of the Solid Electrolyte Interphase on Lithiated-Silicon Electrodes. (Nanowerk News) Researchers have proposed an efficient and stable dual-phase lithium metal anode for Li-S batteries, containing polysulfide-induced solid electrolyte interphase and nanostructured graphene framework at Tsinghua University, appearing on ACS Nano ("Dual-Phase Lithium Metal Anode. In Situ X‑ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode Sudeshna Chattopadhyay,§,† Albert L. Looking for abbreviations of SEI? It is Solid Electrolyte Interface. A solid electrolyte interphase (SEI) is generated on the anode of lithium-ion batteries during the first few charging cycles. Kim 3, Thomas E. A continuum-scale mathematical model has been developed to simulate the growth of the SEI and transport of lithium and electrons through the film. In fact, for the majority of Li-metal batteries with cathodes that do not contain lithium, the initial cycle for the anode is stripping, instead of deposition. When appropriate organic solvents are used as the electrolyte, the solvent decomposes on initial charging and forms a solid layer called the solid electrolyte interphase, which is electrically insulating yet provides significant ionic conductivity. The SEI film is due to electrochemical reduction of species present in the electrolyte. The SEI is formed through chemical and particularly electrochemical side reactions of electrolyte components in the first charging cycle(s) after. Many of these issues are related to the formation and evolution of the solid-electrolyte interphase (SEI) layer between the anode and electrolyte, as a product of electrochemical decomposition. Effect of electrolyte on the nanostructure of the solid electrolyte interphase (SEI) and performance of lithium metal anodes Sunhyung Jurng, Zachary L. Li reacts instantly in contact with liquid electrolytes and rapidly forms an SEI film. Effect of electrolytes on the structure and evolution of the solid electrolyte interphase (SEI) in Li-ion batteries A molecular dynamics study Sang Pil Kim, Adri Van Duin , Vivek B. The artificial solid electrolyte interphase of an anode for a secondary battery including multi-walled carbon nanotubes to protect an underlying anode material in the form of a thin film. anode solid electrolyte interphase (sei) of lithium ion battery characterized by microscopy and spectroscopy by mengyun nie a dissertation submitted in partial fulfillment of the requirements for the degree of doctor of philosophy in chemistry university of rhode island 2014. N2 - To make a Lithium Ion Battery (LIB) reliably rechargeable over many cycles, its graphite-based negative electrode requires the solid electrolyte interphase (SEI) as a protection layer. electrolyte interface. Polymer-inorganic solid-electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions Yue Gao 1, Zhifei Yan1, Jennifer L. High-temperature solid electrolyte interphases (SEI) in graphite electrodes. For cell optimization, vinylene carbonate (VC) was employed as an electrolyte additive to build a stable solid electrolyte interphase (SEI) layer on the electrode. Carney, Alexis Grimaud, Livia Giordano, Nir Pour, Hao-Hsun Chang,David P. - Evaluated capacity retention and identified morphology of solid electrolyte interphase (SEI) with respect to manufacturing parameters or defects • Characterization of porous structure - Explored fluid flow within battery cells based on microfluidics. Role of Solution Structure in Solid Electrolyte Interphase the Solid Electrolyte Interphase in Li-Ion Electrodes in Li Ion Batteries. Experimental Mechanics. 5 Ah graphite/LiFePO4 cells. Here, a significantly improved cycle life of 1000 cycles (80% capacity retention) on a practically insoluble organic cathode material, anthraquinone‐1,5‐disulfonic acid sodium salt, is realized, in KIBs through a solid‐electrolyte interphase (SEI) regulation strategy by ether‐based electrolytes. Solid Edge; Solid Electrolyte Interface; solid. Properties and Fracture of the Solid Electrolyte Interphase in Lithium Ion Batteries. This solid-state electrolyte coating may be regarded as an artificial solid-electrolyte interphase (ASEI) [2]. To gain new insights into the formation of the solid electrolyte interphase (SEI), as a basis for the safe and efficient use of new anode materials, we studied SEI formation on silicon and lithium titanate (LTO) anodes by electrochemical impedance spectroscopy (EIS) and ex situ X-ray photoelectron spectroscopy (XPS) measurements. The highly concentrated electrolyte along with the robust solid electrolyte interphase (SEI) formed therein. The number of PC molecules coordinated with lithium ion is significantly altered and this results in a change of the SEI mechanism at the electrode/electrolyte interface. electrolytes with graphite negative electrodes, and the result shows that unlike the ethylene carbonate (EC)-based electrolyte, the FEC-based electrolyte (EC was totally replaced by FEC) is incapable of forming a protective and effective solid electrolyte interphase (SEI) that protects the electrolyte from runaway reduction on the graphite. [6,7] Both the mechanical and. How Solid-Electrolyte-Interphase Forms in Aqueous Electrolytes Liumin Suo a, Dahyun Oh b, c, Yuxiao Lin d, Zengqing Zhuo e,f, Oleg Borodin g, Tao Gao h, Fei Wang g, h, Akihiro Kushima i, Ziqiang Wang i, Ho-Cheol Kim c, Yue Qi d, Wanli Yang e,. Since the electronically insulating solid state electrolyte inhibits the unwanted electron transfer between the cathode and the electrolyte solution, the electrochemical potential window of the liquid electrolyte could be widened. , In Situ Measurement of Phase Boundary Kinetics during Initial Lithiation of Crystalline Silicon through Picosecond Ultrasonics. Electrolyte and Solid-Electrolyte Interphase Layer in Lithium-Io n Batteries 147 remains constant [Bockris, 1970]. This paper provides a comparison of the conductivities of solid-electrolyte materials being used or developed for use in lithium-ion batteries. Our solid-state batteries provide a major improvement in energy density, safety, and reliability compared to the best Li-ion cells available. Yet, it is inherently difficult to study because of its nanoscale thickness, amorphous composite structure, and air sensitivity. Es ist nach wie vor unklar, ob diese SEI, die die Oberfläche des Anodenmaterials passiviert, eine zwingende Voraussetzung für den sicheren Betrieb von Lithium. In: Chemistry of Materials. Read "The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling, Carbon" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. The model is validated with experimental full charge, discharge, HEV cycle, and aging data from 4. Jayalekshmi was not involved in the study, but her team has recently developed a novel type of solid polymer electrolyte (SPE) based on a polymer blend of PEO and PVP. , 2015; Shin et al. , In Situ Measurement of Phase Boundary Kinetics during Initial Lithiation of Crystalline Silicon through Picosecond Ultrasonics. electrolyte, 12M lithium bis(fluorosulfonyl)imide (LiFSI) salt in DME solvent (12M LiFSI/DME), that can ef-fectively suppress both the Li dendritic growth on the anode and the polysulfide shuttle reactions on the cathode side. Carney, Alexis Grimaud, Livia Giordano, Nir Pour, Hao-Hsun Chang,David P. Pedro de Souza, Kyle C. Study and modeling of the Solid Electrolyte Interphase behavior on nano-silicon anodes by Electrochemical Impedance Spectroscopy Etienne Radvanyia ,1, Kristof Van Havenberghb c, Willy Porchera, Séverine Jouanneaua, Jean-Sébastien Bridelb, Stijn Putb, Sylvain Frangerd,∗ a French. Since the electronically insulating solid state electrolyte inhibits the unwanted electron transfer between the cathode and the electrolyte solution, the electrochemical potential window of the liquid electrolyte could be widened. Rezasadeh-Kalehbasti, Liu, L. lithium and solid electrolyte interphase (SEI), lithium cation migration across the SEI barrier to the SEI/electrolyte interface, and diffusion of solvated ions into electrolyte. Solid electrolyte interphase (SEI) is formed under the first charging at the interface between anode and electrolyte solution in Lithium ion battery (LIB), and governs the performance and the safety. In Situ Investigations of Solid Electrolyte Interphase Formation and Properties in Lithium Ion Batteries by Anton V. This hydrophobic coating expels water molecules from the vicinity of the electrode surface and then, upon charging for the first time, decomposes and forms a stable interphase–a thin mixture of breakdown products that separates the solid anode from the liquid electrolyte. A passivation layer called the solid electrolyte interphase (SEI) is formed on electrode surfaces from decomposition products of electrolytes. It involves charge transfer at the interface between lithium and solid electrolyte interphase (SEI), lithium cation migration across the SEI barrier to the SEI/electrolyte interface, and diffusion of solvated ions into electrolyte. Components in SEI, such as lithium alkyl carbonates and lithium alkoxide salts, are thermally unstable and sensitive to moisture. As a practical application, we have dealt with the solid electrolyte interphase film formation in LIB, focusing on the bifurcation of dimerization reactions between the reduction products, and were able to reproduce the tendency similar to that in the experimental observations. Abstract Lithium-sulfur (Li-S) batteries promise the next-generation energy storage. Materials Science and Engineering, Johns Hopkins University, 2009 A dissertation submitted in partial fulfillment of the requirements for the Degree of Doctor of Philosophy. The performance characteristics of Li-ion batteries are intrinsically linked to evolving nanoscale interfacial electrochemical reactions. LITHIUM-ION BATTERIES: SOLID-ELECTROLYTE INTERPHASE [Perla B Balbuena, Yixuan Wang] on Amazon. J [PDF] Darwin's Brands: Adapting For Success. What is the abbreviation for Solid Electrolyte Interphase? What does SEI stand for? SEI abbreviation stands for Solid Electrolyte Interphase. Properties and Fracture of the Solid Electrolyte Interphase in Lithium Ion Batteries. The electrical double layer forms prior to the formation of SEI at the interface between the Li metal anode and the electrolyte. suffers from electrolyte chemical degradation caused by the formation of an unstable solid electrolyte interphase (SEI). Electrode/Electrolyte Interphase Characterization in Solid Oxide Fuel Cells, Hydrogen Energy - Challenges and Perspectives, Dragica Minic, IntechOpen, DOI: 10. Joule 3, 1-15, November 20, 2019 ª 2019 Elsevier Inc. solid−electrolyte interphase (SEI), a passivating layer that forms on the surface of almost all lithium-ion battery negative electrodes as a result of electrochemical decomposition of the electrolyte. (Nanowerk News) Researchers have proposed an efficient and stable dual-phase lithium metal anode for Li-S batteries, containing polysulfide-induced solid electrolyte interphase and nanostructured graphene framework at Tsinghua University, appearing on ACS Nano ("Dual-Phase Lithium Metal Anode. , Guduru, P. For the sake of this article, we will stick to the solid electrolyte interface. The electrochemical oxidation of its surface atoms results in the liberation of cations into the electrolyte. title = "Surface chemistry and morphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes", abstract = "Silicon nanowires (SiNWs) have the potential to perform as anodes for lithium-ion batteries with a much higher energy density than graphite. Despite its importance, it remains. 5 (PO 4) 3-polypropylene (LAGP-PP) based separator during charging and discharging is proposed and demonstrated. Overall experimental results confirm the majority of species suggested by the simulation. The formation and growth mechanism of the. The use of the artificial solid electrolyte interphase enables rapid diffusion and stable deposition of lithium to inhibit the formation of dendrites. In this paper, the growing solid electrolyte interphase (SEI) and deposited manganese ions of the silicon anode's surface of the spinel lithium manganese oxide LiMn₂O₄/silicon full cells are quantitatively studied during electrochemical cycling, and the SEI performances are tested by differential scanning calorimetry to find out the. This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. (∼400% volume expansion) and the formation of a solid electrolyte interphase (SEI) on silicon leads to severe capacity fade and slow rates of charge and discharge. Electron transfer in the solid-electrolyte interphase Miller, Thomas F. Battery performance, irreversible charge "loss", rate capability, cyclability, exfoliation of graphite and safety are highly dependent on the quality of. 12 The importance of the interphase electrodes in liquid nonaqueous and polymer electrolytes. The composition of the SEI layer on Si/MC electrodes, cycled with and without VC-containing electrolytes for several. edu : SEI layers are known to be formed on the surface of Li batteries due to side reactions caused mainly by reduction or oxidation of solvents at the surface of anodes and cathodes, although other electrolyte compo. - Mn dissolves from positive electrodes and plates on negative electrode surface. Introduction Lithium metal is recognized as the optimal choice for anode mate-rial to achieve high energy density batteries because it has low negative. lithium and solid electrolyte interphase (SEI), lithium cation migration across the SEI barrier to the SEI/electrolyte interface, and diffusion of solvated ions into electrolyte. In fact, for the majority of Li-metal batteries with cathodes that do not contain lithium, the initial cycle for the anode is stripping, instead of deposition. suffers from electrolyte chemical degradation caused by the formation of an unstable solid electrolyte interphase (SEI). Solid-electrolyte interphase (SEI) is the key component that enables all advanced electrochemical devices, the best representative of which is Li-ion battery (LIB). On the one hand, high order pseudo-2D electrochemical models are predictive and reproduce in a good way the evolutions of capacity and power loss during ageing. Electrode/Electrolyte Interphase Characterization in Solid Oxide Fuel Cells, Hydrogen Energy - Challenges and Perspectives, Dragica Minic, IntechOpen, DOI: 10. The passivating solid electrolyte interphase (SEI) layer forms at the surface of the negative-electrode active material in lithium-ion cells. Chaudhari2, Lawrence R. , In Situ Measurement of Phase Boundary Kinetics during Initial Lithiation of Crystalline Silicon through Picosecond Ultrasonics. The number of PC molecules coordinated with lithium ion is significantly altered and this results in a change of the SEI mechanism at the electrode/electrolyte interface. This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The role of the solid electrolyte interphase layer in preventing Li dendrite growth in solid-state batteries. lithium sulfur (Li−S) batteries lead to the formation of solid-electrolyte interphase (SEI) layers, which are the major reason behind severe capacity fading in these systems. The solid–electrolyte-interphase layer is extremely important for reversible electrochemical cycling of Li-ion batteries. The interphase prevents further decomposition of the electrolyte after the second charge. Polymer electrolyte has moderate contact with cathode due to the elasticity and deformability of organic polymers. Carney, Alexis Grimaud, Livia Giordano, Nir Pour, Hao-Hsun Chang,David P. / Nanoscale investigation of solid electrolyte interphase inhibition on li-ion battery MnO electrodes via atomic layer deposition of Al 2 O 3. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy - Volume 20 Issue 4 - Raymond R. The team found that the origin of whiskers in a lithium metal battery lies in the solid-electrolyte interphase (SEI), which is a film where the solid lithium surface of the anode meets the liquid electrolyte. Predictions of Ethylene Carbonate Breakdown & Solid Electrolyte Interphase (SEI) Onset Collaborators Kevin Leung (Sandia National Lab) Joanne Budzien (Frostburg State) Significance • The stability and safety of many electrochemical systems for electrical energy storage depend on a critical solid-electrolyte interphase (SEI), which forms. This solid-state electrolyte coating may be regarded as an artificial solid-electrolyte interphase (ASEI) [2]. pc客户端连续签到 7天抢福利 pc客户端 免费蓝光播放 pc客户端 3倍流畅播放 pc客户端 提前一小时追剧 pc客户端 自动更新下载剧集. A paper on their work is published in the journal. Authors of this Perspective: Magali Gauthier, Thomas J. They see it as a power storage "game changer. The solid electrolyte interphase that forms between lithium metal and these liquid electrolytes is brittle which causes a highly irregular current distribution at the anode, resulting in the formation of lithium metal protrusions. The conventional solid-electrolyte interphase (SEI) layer formed by direct contact of Li metal anode with liquid electrolyte is inorganic dominated and too fragile to withstand the enormous volume fluctuations during Li plating and stripping cycling. Battery technology has finally reached the point that you can drive an electric vehicle without constant range anxiety, but you still have to plan ahead for charging. The use of the artificial solid electrolyte interphase enables rapid diffusion and stable deposition of lithium to inhibit the formation of dendrites. Its ability to form a. 有机溶剂常常在充电时破坏石墨的结构,导致其剥脱,并在其表面形成固体电解质膜(solid electrolyte interphase,SEI)导致电极钝化。 有机溶剂还带来易燃、易爆等安全性问题。. Stabilizing Li₁₀SnP₂S₁₂/Li Interface via an in Situ Formed Solid Electrolyte Interphase Layer Author: Zheng, Bizhu, Zhu, Jianping, Wang, Hongchun, Feng, Min. Materials Science and Engineering, Johns Hopkins University, 2009 A dissertation submitted in partial fulfillment of the requirements for the Degree of Doctor of Philosophy. 8,10 At the working potential of anodes, electrolytes are not stable and consequently are reduced on the anode surface to form the SEI, which consists of a complex composition of inorganic and organic lithium compounds. The added KPF6 increased the fraction of inorganic salts in the solid electrolyte interface, making it thinner and more Li+ conductive. [6,7] Both the mechanical and. For cell optimization, vinylene carbonate (VC) was employed as an electrolyte additive to build a stable solid electrolyte interphase (SEI) layer on the electrode. It kinetically stabilizes electrolytes at potentials far beyond their thermodynamic stability limits, so that cell reactions could proceed reversibly. They see it as a power storage "game changer. Solid Electrolyte Interphase ist eine bisher kaum verstandene Grenzflächenschicht, die aus der partiellen Zersetzung von Batterieelektrolyten in der Gegenwart von Lithium resultiert. Brown, Jiyeon Kim, and Brett L. Here, a significantly improved cycle life of 1000 cycles (80% capacity retention) on a practically insoluble organic cathode material, anthraquinone‐1,5‐disulfonic acid sodium salt, is realized, in KIBs through a solid‐electrolyte interphase (SEI) regulation strategy by ether‐based electrolytes. NEI is actively involved in producing different compositions of sulfide-based solid electrolyte materials, including our own patent-pending LSPS. The PNNL team found that the origin of whiskers in a lithium metal battery lies in a structure known as the "SEI" or solid-electrolyte interphase, a film where the solid lithium surface of the. composite material. Gray2, Xin He3, Daiwei Wang4, Tianhang Chen4, Qingquan Huang4, Yuguang C. Haoshen Zhou took a moment to outline the challenges for researchers interfacing electrodes with solid electrolytes. The added KPF6 increased the fraction of inorganic salts in the solid electrolyte interface, making it thinner and more Li+ conductive. However, when silicon electrodes are lithiated, they form a solid-electrolyte interphase (SEI) at their surface. Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation. The solid electrolyte interphase (SEI), which forms spontaneously at the electrode-electrolyte interface, plays a critical role in the performance and safety of Li-ion batteries, but little is known about its structure from in-situ observations. File:SEI layer formation on silicon. Li1, Haiying Wang2, Seong H. What is the abbreviation for Solid Electrolyte Interphase? What does SEI stand for? SEI abbreviation stands for Solid Electrolyte Interphase. Try following some people or topics that interest you. File:SEI layer formation on silicon. the electrolyte (the so-called 'solid-electrolyte interphase', SEI). Enjoy the videos and music you love, upload original content, and share it all with friends, family, and the world on YouTube. Adamczyk, Daan Hein Alsem, Sheng Dai, Nancy J. electrolytes with graphite negative electrodes, and the result shows that unlike the ethylene carbonate (EC)-based electrolyte, the FEC-based electrolyte (EC was totally replaced by FEC) is incapable of forming a protective and effective solid electrolyte interphase (SEI) that protects the electrolyte from runaway reduction on the graphite. Note that some people also called Solid Electrolyte Interface as Solid Electrolyte Interphase (SEI), both the terms are used interchangeably overall research papers and hence it is hard to argue on which is the correct term. However, current technology is limited in charging rate, power density, reliability, and safety. The chemical structure of the surface and interior of the SEI strongly affects the cycling performance of the anode. , the current density. It is important to understand what SEI is at a high level, as this component is one of the main contributing factors to Li-ion battery aging and resistance. It kinetically stabilizes electrolytes at potentials far beyond their thermodynamic stability limits, so that cell reactions could proceed reversibly. Joule 3, 1–15, November 20, 2019 ª 2019 Elsevier Inc. This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. Fenning, Simon F. Lithium (Li) metal is a promising anode material for high‐energy density batteries. The fact-checkers, whose work is more and more important for those who prefer facts over lies, police the line between fact and falsehood on a day-to-day basis, and do a great job. Today, my small contribution is to pass along a very good overview that reflects on one of Trump’s favorite overarching falsehoods. Namely: Trump describes an America in which everything was going down the tubes under  Obama, which is why we needed Trump to make America great again. And he claims that this project has come to fruition, with America setting records for prosperity under his leadership and guidance. “Obama bad; Trump good” is pretty much his analysis in all areas and measurement of U.S. activity, especially economically. Even if this were true, it would reflect poorly on Trump’s character, but it has the added problem of being false, a big lie made up of many small ones. Personally, I don’t assume that all economic measurements directly reflect the leadership of whoever occupies the Oval Office, nor am I smart enough to figure out what causes what in the economy. But the idea that presidents get the credit or the blame for the economy during their tenure is a political fact of life. Trump, in his adorable, immodest mendacity, not only claims credit for everything good that happens in the economy, but tells people, literally and specifically, that they have to vote for him even if they hate him, because without his guidance, their 401(k) accounts “will go down the tubes.” That would be offensive even if it were true, but it is utterly false. The stock market has been on a 10-year run of steady gains that began in 2009, the year Barack Obama was inaugurated. But why would anyone care about that? It’s only an unarguable, stubborn fact. Still, speaking of facts, there are so many measurements and indicators of how the economy is doing, that those not committed to an honest investigation can find evidence for whatever they want to believe. Trump and his most committed followers want to believe that everything was terrible under Barack Obama and great under Trump. That’s baloney. Anyone who believes that believes something false. And a series of charts and graphs published Monday in the Washington Post and explained by Economics Correspondent Heather Long provides the data that tells the tale. The details are complicated. Click through to the link above and you’ll learn much. But the overview is pretty simply this: The U.S. economy had a major meltdown in the last year of the George W. Bush presidency. Again, I’m not smart enough to know how much of this was Bush’s “fault.” But he had been in office for six years when the trouble started. So, if it’s ever reasonable to hold a president accountable for the performance of the economy, the timeline is bad for Bush. GDP growth went negative. Job growth fell sharply and then went negative. Median household income shrank. The Dow Jones Industrial Average dropped by more than 5,000 points! U.S. manufacturing output plunged, as did average home values, as did average hourly wages, as did measures of consumer confidence and most other indicators of economic health. (Backup for that is contained in the Post piece I linked to above.) Barack Obama inherited that mess of falling numbers, which continued during his first year in office, 2009, as he put in place policies designed to turn it around. By 2010, Obama’s second year, pretty much all of the negative numbers had turned positive. By the time Obama was up for reelection in 2012, all of them were headed in the right direction, which is certainly among the reasons voters gave him a second term by a solid (not landslide) margin. Basically, all of those good numbers continued throughout the second Obama term. The U.S. GDP, probably the single best measure of how the economy is doing, grew by 2.9 percent in 2015, which was Obama’s seventh year in office and was the best GDP growth number since before the crash of the late Bush years. GDP growth slowed to 1.6 percent in 2016, which may have been among the indicators that supported Trump’s campaign-year argument that everything was going to hell and only he could fix it. During the first year of Trump, GDP growth grew to 2.4 percent, which is decent but not great and anyway, a reasonable person would acknowledge that — to the degree that economic performance is to the credit or blame of the president — the performance in the first year of a new president is a mixture of the old and new policies. In Trump’s second year, 2018, the GDP grew 2.9 percent, equaling Obama’s best year, and so far in 2019, the growth rate has fallen to 2.1 percent, a mediocre number and a decline for which Trump presumably accepts no responsibility and blames either Nancy Pelosi, Ilhan Omar or, if he can swing it, Barack Obama. I suppose it’s natural for a president to want to take credit for everything good that happens on his (or someday her) watch, but not the blame for anything bad. Trump is more blatant about this than most. If we judge by his bad but remarkably steady approval ratings (today, according to the average maintained by 538.com, it’s 41.9 approval/ 53.7 disapproval) the pretty-good economy is not winning him new supporters, nor is his constant exaggeration of his accomplishments costing him many old ones). I already offered it above, but the full Washington Post workup of these numbers, and commentary/explanation by economics correspondent Heather Long, are here. On a related matter, if you care about what used to be called fiscal conservatism, which is the belief that federal debt and deficit matter, here’s a New York Times analysis, based on Congressional Budget Office data, suggesting that the annual budget deficit (that’s the amount the government borrows every year reflecting that amount by which federal spending exceeds revenues) which fell steadily during the Obama years, from a peak of $1.4 trillion at the beginning of the Obama administration, to $585 billion in 2016 (Obama’s last year in office), will be back up to $960 billion this fiscal year, and back over $1 trillion in 2020. (Here’s the New York Times piece detailing those numbers.) Trump is currently floating various tax cuts for the rich and the poor that will presumably worsen those projections, if passed. As the Times piece reported: